Structurally Stimulated Deprotonation/Alumination of the TMP Anion
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چکیده
منابع مشابه
Structurally Stimulated Deprotonation/Alumination of the TMP Anion**
Derived from the cyclic secondary amine 2,2,6,6-tetramethylpiperidine [TMP(H)] by removal of its nitrogen-attached hydrogen atom, the TMP anion 1 has had a 40 year career in the business of selective proton abstraction. Possessing attributes of high steric bulk and low nucleophilicity, without any b-hydrogen atoms (the presence of which often disadvantages its diisopropylamido analogue through ...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2010
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.201000181